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Green Synthesis of Reduced Graphene Oxide-Cofe2o4 Nanocomposite As a Highly Efficient Visible-Light-Driven Catalyst in Photocatalysis and Photo Fenton-Like Reaction Publisher



Mazarji M1 ; Esmaili H2 ; Bidhendi GN3 ; Mahmoodi NM4 ; Minkina T1 ; Sushkova S1 ; Mandzhieva S1 ; Barakhov A1 ; Moghtaderi H5 ; Bhatnagar A6
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Source: Materials Science and Engineering: B Published:2021


Abstract

In this study, reduced graphene oxide (rGO)-cobalt ferrite (CoFe2O4) nanocomposite was synthesized by green mechano-thermal methods. The synthesized material was characterized using XRD, FTIR, SEM, TGA, UV–vis, VSM, and XPS. The as-prepared rGO-CoFe2O4 with a suitable band gap of 1.89 eV was explored as a photoactive material in visible-light degradation of two basic dyes namely, basic red 46 (BR46) and basic red 18 (BR18). In photocatalysis, BR46 and BR18 were degraded up to 76 and 79%, with apparent rate constants of 0.0051 and 0.0045 min−1, respectively. In the photo Fenton-like reaction, the efficiency and the rate constant were enhanced compared to photocatalysis and found to be 88% and 0.0088 min−1 for BR46 and 90% and 0.0093 min−1 for BR18. The hydroxyl radicals were the main active species responsible in the visible/rGO-CoFe2O4/H2O2 system. The in vitro study on human umbilical vein endothelial cells (HUVEC) suggested the non-cytotoxicity of as-prepared nanocomposite. © 2021 Elsevier B.V.
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