Selective Aqueous Oxidation of Alcohols Catalyzed by Copper (Ii) Phthalocyanine Nanoparticles

Selective Aqueous Oxidation of Alcohols Catalyzed by Copper (Ii) Phthalocyanine Nanoparticles Publisher

Kheirjou S¹ ; Kheirjou R² ; Rezayan AH³ ; Shakourianfard M¹ ; Mahmoudi Hashemi M¹

Source: Comptes Rendus Chimie Published:2016

Abstract

A new catalyst based on metallophthalocyanine nanoparticles has been synthesized and characterized by scanning electron microscopy (SEM). The aqueous oxidation of alcohols to the corresponding carbonyl compounds (aldehydes and ketones) has been studied using tetra-n-butyl-ammonium-peroxo-monosulfate (n-Bu4NHSO5) as an oxidant and a catalytic system consisting of copper (II) phthalocyanine nanoparticles in water. The highly selective oxidation gave excellent yields of related aldehydes or ketones without remarkable over-oxidation of the carboxylic acids. Organic co-solvents, surfactants, and co-catalysts were not used in this catalytic strategy. This strategy was green and time effective. The oxidant's by-product (TBAHSO4) and catalyst can be efficiently recovered and reused several times without any significant change of catalytic activity.

2. Magnetic Cufe2o4 Nanoparticles As an Efficient Catalyst for the Oxidation of Alcohols to Carbonyl Compounds in the Presence of Oxone As an Oxidant, Bulgarian Chemical Communications (2015)

Experts (# of related papers)

Mehdi Khoobi (1)

Mohammad Mahdavi (1)

Style	Citing Format
MLA	Kheirjou S, et al.. "Selective Aqueous Oxidation of Alcohols Catalyzed by Copper (Ii) Phthalocyanine Nanoparticles." Comptes Rendus Chimie, vol. 19, no. 3, 2016, pp. 314-319.
APA	Kheirjou S, Kheirjou R, Rezayan AH, Shakourianfard M, Mahmoudi Hashemi M (2016). Selective Aqueous Oxidation of Alcohols Catalyzed by Copper (Ii) Phthalocyanine Nanoparticles. Comptes Rendus Chimie, 19(3), 314-319.
Chicago	Kheirjou S, Kheirjou R, Rezayan AH, Shakourianfard M, Mahmoudi Hashemi M. "Selective Aqueous Oxidation of Alcohols Catalyzed by Copper (Ii) Phthalocyanine Nanoparticles." Comptes Rendus Chimie 19, no. 3 (2016): 314-319.
Harvard	Kheirjou S et al. (2016) 'Selective Aqueous Oxidation of Alcohols Catalyzed by Copper (Ii) Phthalocyanine Nanoparticles', Comptes Rendus Chimie, 19(3), pp. 314-319.
Vancouver	Kheirjou S, Kheirjou R, Rezayan AH, Shakourianfard M, Mahmoudi Hashemi M. Selective Aqueous Oxidation of Alcohols Catalyzed by Copper (Ii) Phthalocyanine Nanoparticles. Comptes Rendus Chimie. 2016;19(3):314-319.
BibTex	@article{ author = {Kheirjou S and Kheirjou R and Rezayan AH and Shakourianfard M and Mahmoudi Hashemi M}, title = {Selective Aqueous Oxidation of Alcohols Catalyzed by Copper (Ii) Phthalocyanine Nanoparticles}, journal = {Comptes Rendus Chimie}, volume = {19}, number = {3}, pages = {314-319}, year = {2016} }
RIS	TY - JOUR AU - Kheirjou S AU - Kheirjou R AU - Rezayan AH AU - Shakourianfard M AU - Mahmoudi Hashemi M TI - Selective Aqueous Oxidation of Alcohols Catalyzed by Copper (Ii) Phthalocyanine Nanoparticles JO - Comptes Rendus Chimie VL - 19 IS - 3 SP - 314 EP - 319 PY - 2016 ER -

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