Imidazole-Functionalized Nitrogen-Rich Mg-Al-Co3 Layered Double Hydroxide for Developing Highly Crosslinkable Epoxy With High Thermal and Mechanical Properties

Imidazole-Functionalized Nitrogen-Rich Mg-Al-Co3 Layered Double Hydroxide for Developing Highly Crosslinkable Epoxy With High Thermal and Mechanical Properties Publisher

Seidi F¹ ; Jouyandeh M^{2, 3} ; Paran SMR² ; Esmaeili A⁴ ; Karami Z² ; Livi S⁵ ; Habibzadeh S⁶ ; Vahabi H³ ; Ganjali MR^{2, 7} ; Saeb MR³

Source: Colloids and Surfaces A: Physicochemical and Engineering Aspects Published:2021

Abstract

Ionic liquid-based N-octadecyl-N'-octadecyl imidazolium iodide functionalized layered double hydroxide (LDH-IM) was synthesized for manufacturing high-performance epoxy nanocomposites. Nonisothermal differential scanning calorimetry (DSC) was performed to study cure kinetics of epoxy reinforced قث with LDH and LDH-IM. Incorporation of Mg-Al-CO3 LDH into epoxy hindered the curing reaction, as detected by dimensionless Cure Index (CI). By contrast, epoxy/LDH-IM cured Good and Excellent due to imidazolium ionic liquid. Higher activation energy for completely cured epoxy/LDH-IM nanocomposite was obtained compared to epoxy and epoxy/LDH nanocomposites. The curing reaction rate was obtained by calculation of the orders of instantaneous autocatalytic and non-catalytic reactions, and optimal kinetic parameters based on isoconversional methods were in good agreement with experimental cure reaction rates. Lower value of Tg for epoxy/LDH nanocomposite compared to the neat epoxy signified weak interactions between Mg-Al-CO3-LDH and epoxy matrix, while a higher Tg was obtained for epoxy/LDH-IM. Network degradation kinetics of the samples was also investigated. The higher decomposition activation energy for epoxy/LDH-IM approved strong interfacial adhesion in the assigned system. The highly reactive nature of the developed LDH-IM gives reason for its usage for developing highly curable epoxy with high thermal and mechanical properties. © 2020 Elsevier B.V.

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Style	Citing Format
MLA	Seidi F, et al.. "Imidazole-Functionalized Nitrogen-Rich Mg-Al-Co3 Layered Double Hydroxide for Developing Highly Crosslinkable Epoxy With High Thermal and Mechanical Properties." Colloids and Surfaces A: Physicochemical and Engineering Aspects, vol. 611, no. , 2021, pp. -.
APA	Seidi F, Jouyandeh M, Paran SMR, Esmaeili A, Karami Z, Livi S, Habibzadeh S, Vahabi H, Ganjali MR, Saeb MR (2021). Imidazole-Functionalized Nitrogen-Rich Mg-Al-Co3 Layered Double Hydroxide for Developing Highly Crosslinkable Epoxy With High Thermal and Mechanical Properties. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 611(), -.
Chicago	Seidi F, Jouyandeh M, Paran SMR, Esmaeili A, Karami Z, Livi S, Habibzadeh S, Vahabi H, Ganjali MR, Saeb MR. "Imidazole-Functionalized Nitrogen-Rich Mg-Al-Co3 Layered Double Hydroxide for Developing Highly Crosslinkable Epoxy With High Thermal and Mechanical Properties." Colloids and Surfaces A: Physicochemical and Engineering Aspects 611, no. (2021): -.
Harvard	Seidi F et al. (2021) 'Imidazole-Functionalized Nitrogen-Rich Mg-Al-Co3 Layered Double Hydroxide for Developing Highly Crosslinkable Epoxy With High Thermal and Mechanical Properties', Colloids and Surfaces A: Physicochemical and Engineering Aspects, 611(), pp. -.
Vancouver	Seidi F, Jouyandeh M, Paran SMR, Esmaeili A, Karami Z, Livi S, et al.. Imidazole-Functionalized Nitrogen-Rich Mg-Al-Co3 Layered Double Hydroxide for Developing Highly Crosslinkable Epoxy With High Thermal and Mechanical Properties. Colloids and Surfaces A: Physicochemical and Engineering Aspects. 2021;611():-.
BibTex	@article{ author = {Seidi F and Jouyandeh M and Paran SMR and Esmaeili A and Karami Z and Livi S and Habibzadeh S and Vahabi H and Ganjali MR and Saeb MR}, title = {Imidazole-Functionalized Nitrogen-Rich Mg-Al-Co3 Layered Double Hydroxide for Developing Highly Crosslinkable Epoxy With High Thermal and Mechanical Properties}, journal = {Colloids and Surfaces A: Physicochemical and Engineering Aspects}, volume = {611}, number = {}, pages = {-}, year = {2021} }
RIS	TY - JOUR AU - Seidi F AU - Jouyandeh M AU - Paran SMR AU - Esmaeili A AU - Karami Z AU - Livi S AU - Habibzadeh S AU - Vahabi H AU - Ganjali MR AU - Saeb MR TI - Imidazole-Functionalized Nitrogen-Rich Mg-Al-Co3 Layered Double Hydroxide for Developing Highly Crosslinkable Epoxy With High Thermal and Mechanical Properties JO - Colloids and Surfaces A: Physicochemical and Engineering Aspects VL - 611 IS - SP - EP - PY - 2021 ER -

Style

Citing Format

MLA

Seidi F, et al.. "Imidazole-Functionalized Nitrogen-Rich Mg-Al-Co3 Layered Double Hydroxide for Developing Highly Crosslinkable Epoxy With High Thermal and Mechanical Properties." Colloids and Surfaces A: Physicochemical and Engineering Aspects, vol. 611, no. , 2021, pp. -.

APA

Seidi F, Jouyandeh M, Paran SMR, Esmaeili A, Karami Z, Livi S, Habibzadeh S, Vahabi H, Ganjali MR, Saeb MR (2021). Imidazole-Functionalized Nitrogen-Rich Mg-Al-Co3 Layered Double Hydroxide for Developing Highly Crosslinkable Epoxy With High Thermal and Mechanical Properties. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 611(), -.

Chicago

Seidi F, Jouyandeh M, Paran SMR, Esmaeili A, Karami Z, Livi S, Habibzadeh S, Vahabi H, Ganjali MR, Saeb MR. "Imidazole-Functionalized Nitrogen-Rich Mg-Al-Co3 Layered Double Hydroxide for Developing Highly Crosslinkable Epoxy With High Thermal and Mechanical Properties." Colloids and Surfaces A: Physicochemical and Engineering Aspects 611, no. (2021): -.

Harvard

Seidi F et al. (2021) 'Imidazole-Functionalized Nitrogen-Rich Mg-Al-Co3 Layered Double Hydroxide for Developing Highly Crosslinkable Epoxy With High Thermal and Mechanical Properties', Colloids and Surfaces A: Physicochemical and Engineering Aspects, 611(), pp. -.

Vancouver

Seidi F, Jouyandeh M, Paran SMR, Esmaeili A, Karami Z, Livi S, et al.. Imidazole-Functionalized Nitrogen-Rich Mg-Al-Co3 Layered Double Hydroxide for Developing Highly Crosslinkable Epoxy With High Thermal and Mechanical Properties. Colloids and Surfaces A: Physicochemical and Engineering Aspects. 2021;611():-.

BibTex

@article{ author = {Seidi F and Jouyandeh M and Paran SMR and Esmaeili A and Karami Z and Livi S and Habibzadeh S and Vahabi H and Ganjali MR and Saeb MR}, title = {Imidazole-Functionalized Nitrogen-Rich Mg-Al-Co3 Layered Double Hydroxide for Developing Highly Crosslinkable Epoxy With High Thermal and Mechanical Properties}, journal = {Colloids and Surfaces A: Physicochemical and Engineering Aspects}, volume = {611}, number = {}, pages = {-}, year = {2021} }

RIS

TY - JOUR
AU - Seidi F
AU - Jouyandeh M
AU - Paran SMR
AU - Esmaeili A
AU - Karami Z
AU - Livi S
AU - Habibzadeh S
AU - Vahabi H
AU - Ganjali MR
AU - Saeb MR
TI - Imidazole-Functionalized Nitrogen-Rich Mg-Al-Co3 Layered Double Hydroxide for Developing Highly Crosslinkable Epoxy With High Thermal and Mechanical Properties
JO - Colloids and Surfaces A: Physicochemical and Engineering Aspects
VL - 611
IS -
SP -
EP -
PY - 2021
ER -

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